|
Document Type |
: |
Article In Journal |
|
Document Title |
: |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile-3-amino-1- phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) 2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile-3-amino-1- phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
|
Subject |
: |
Chemistry |
|
Document Language |
: |
English |
|
Abstract |
: |
The asymmetric unit of the 5:3 title co-crystal of 2-amino-4-phenyl-5,6- dihydro-benzo[h]quinoline-3-carbonitrile and 3-amino-1-phenyl-9,10-dihydro- phenanthrene-2,4-dicarbonitrile, 0.625C 20H 15N 3.0.375C 22H 15N 3, has the atoms of the fused-ring system and those of the amino, cyano and phenyl substitutents overlapped. The fused-ring system is buckled owing to the ethyl-ene linkage in the central ring, the two flanking aromatic rings being twisted by 20.1 (1)°. This ethyl-ene portion is disordered over two positions in a 1:1 ratio. The phenyl ring is twisted by 69.5 (1)° relative to the amino- and cyano-bearing aromatic ring. In the crystal, two molecules are linked by an N - H⋯N hydrogen bond, generating a a helical chain along [010]. |
|
ISSN |
: |
1600-5368 |
|
Journal Name |
: |
Acta Crystallographica Section E: Structure Reports Online |
|
Volume |
: |
67 |
|
Issue Number |
: |
11 |
|
Publishing Year |
: |
1432 AH
2011 AD |
|
Article Type |
: |
Article |
|
Added Date |
: |
Monday, February 20, 2012 |
|
Researchers
| عبدالله محمد عسيري | Asiri, Abdullah Mohamed | Researcher | Doctorate | aasiri2@kau.edu.sa |
| عبدالرحمن عبيد اليوبي | Al-Youbia, Abdulrahman Obaid | Researcher | Doctorate | aalyoubi@kau.edu.sa |
| حسن مصطفى فيض الله | Faidallah, Hassan Mostafa | Researcher | Doctorate | HFAIDALLAH@kau.edu.sa |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
|